Paya (Impa s granddaughter) quickly falls for the hero, but doesn t realize it at first, thinking she s sick.
And that was before the platform opened up verification applications to everyone.
The reason Aelita fell for Jeremie in Code Lyoko seems to be his persistence in helping and trying to make her happy without seeking thanks or reward.
In The Hunger Games, Katniss initially does not want to fall in love or have children.
The pilot manga chapter directly alluded to this trope.
(And if you count gentle and awkward Theodore as a love interest of sorts, he also qualifies.